Comparative Study on Pyrolysis Kinetics Behavior and High-Temperature Fast Pyrolysis Product Analysis of Coastal Zone and Land Biomasses

doi:10.1021/acsomega.1c06363

	Comparative Study on Pyrolysis Kinetics Behavior and High-Temperature Fast Pyrolysis Product Analysis of Coastal Zone and Land Biomasses
	Li, Jie1 ; Shang, Yanchao 2; Wei, Wei 2; Liu, Zhengyi3 ; Qiao, Yingyun 2; Qin, Song3 ; Tian, Yuanyu 2
发表期刊	ACS OMEGA
ISSN	2470-1343
	2022-03-29
卷号	7 期号:12 页码:10144-10155
DOI	10.1021/acsomega.1c06363
通讯作者	Liu, Zhengyi([email protected])
英文摘要	The pyrolysis characteristics of land biomass (corn stalks (Cs), pine sawdust (Ps)) and coastal zone biomass (Jerusalem artichoke stalks (JAs) and reed (Re)) were investigated based on thermogravimetric analysis (TGA) and products' analysis. The kinetic parameters were obtained by three isoconversional methods (Friedman, KAS, and FWO) and one model-fitting method (DAEM). The simultaneous effect of high temperature (700-900 degrees C) and high heating rate (1000 degrees C/s) on the pyrolysis product simulating the typical conditions of a fluidized bed gasifier was studied. TGA showed that high heating rates deepen the thermal cracking process of biomass. Compared with the land biomass, the initial decomposition temperature (Ti) of the coastal biomass is reduced significantly owing to its higher proportion of hemicellulose. These methods agree with the trends shown by the activation energy (Ea) distribution calculated, with fluctuations between 160 and 350 kJ/mol. The mean value activation energies of Re and JAs were higher than those of Cs and Ps between 10% and 90% conversion. The DAEM model showed that Cs and JAs have a good linear relationship between ln A and Ea during the main pyrolysis stage, while Ps and Re are relatively weaker. The kinetic compensation effect was evident for Cs and JAs during the main thermal cracking stage. Py-GC-MS results confirmed that phenols, hydrocarbons, PAHs, and oxygen heterocycle compounds were strongly present in the released volatile products. High-temperature fast pyrolysis of JAs produced a larger amount of PAH compounds than from Cs, Ps, and Re. A larger amount of hydrocarbons and phenols was generated from high-temperature fast pyrolysis of Ps. Some oxygen-containing volatiles are easily converted into aromatic products with higher stability under high temperature.
资助机构	Taishan Scholar Foundation of Shandong Province ; Department of Science and Technology of Shanxi Province
收录类别	SCI
语种	英语
关键词[WOS]	3 MAJOR COMPONENTS ; THERMAL-BEHAVIOR ; ACTIVATION-ENERGY ; HEATING RATE ; TG-FTIR ; PY-GC/MS ; MECHANISM ; CELLULOSE ; MODEL
研究领域[WOS]	Chemistry
WOS记录号	WOS:000783983200018
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/37572
专题	海岸带生物学与生物资源利用重点实验室海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
通讯作者	Liu, Zhengyi
作者单位	1.Shandong Univ Sci & Technol, Coll Safety & Environm Engn, Qingdao 266590, Shandong, Peoples R China 2.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Li, Jie,Shang, Yanchao,Wei, Wei,et al. Comparative Study on Pyrolysis Kinetics Behavior and High-Temperature Fast Pyrolysis Product Analysis of Coastal Zone and Land Biomasses[J]. ACS OMEGA,2022,7(12):10144-10155.
APA	Li, Jie.,Shang, Yanchao.,Wei, Wei.,Liu, Zhengyi.,Qiao, Yingyun.,...&Tian, Yuanyu.(2022).Comparative Study on Pyrolysis Kinetics Behavior and High-Temperature Fast Pyrolysis Product Analysis of Coastal Zone and Land Biomasses.ACS OMEGA,7(12),10144-10155.
MLA	Li, Jie,et al."Comparative Study on Pyrolysis Kinetics Behavior and High-Temperature Fast Pyrolysis Product Analysis of Coastal Zone and Land Biomasses".ACS OMEGA 7.12(2022):10144-10155.