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Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions
Cong Yua ;  Olof Ramstrma ;  Klaus Mosbacha
发表期刊Analytical letters
ISSN0003-2719
1997
卷号30期号:12页码:2123-2140
英文摘要Molecularly imprinted polymers prepared using acrylamide as the hydrogen bonding functional monomer exhibited good enantiomeric recognition properties in aqueous solutions. Our results indicate that the recognition improved with increased mobile phase water percentage and ionic strength, and was also very much pH dependent upon the ionisation properties of the sample molecules. The results can be interpreted in terms of specific hydrophobic interactions between the enantiomeric species and the recognition sites of imprinted polymers. A study of substrate selectivity showed differences between a pure organic system and a water/organic system as the mobile phases. The hydrophobicity of the test compounds was found to be an important parameter in determining the selectivity.
语种英语
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/2979
专题科研共享资源
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Cong Yua, Olof Ramstrma, Klaus Mosbacha. Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions[J]. Analytical letters,1997,30(12):2123-2140.
APA Cong Yua, Olof Ramstrma,& Klaus Mosbacha.(1997).Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions.Analytical letters,30(12),2123-2140.
MLA Cong Yua,et al."Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions".Analytical letters 30.12(1997):2123-2140.
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