Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions | |
Cong Yua ; Olof Ramstrma ; Klaus Mosbacha | |
发表期刊 | Analytical letters |
ISSN | 0003-2719 |
1997 | |
卷号 | 30期号:12页码:2123-2140 |
英文摘要 | Molecularly imprinted polymers prepared using acrylamide as the hydrogen bonding functional monomer exhibited good enantiomeric recognition properties in aqueous solutions. Our results indicate that the recognition improved with increased mobile phase water percentage and ionic strength, and was also very much pH dependent upon the ionisation properties of the sample molecules. The results can be interpreted in terms of specific hydrophobic interactions between the enantiomeric species and the recognition sites of imprinted polymers. A study of substrate selectivity showed differences between a pure organic system and a water/organic system as the mobile phases. The hydrophobicity of the test compounds was found to be an important parameter in determining the selectivity. |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/2979 |
专题 | 科研共享资源 |
推荐引用方式 GB/T 7714 | Cong Yua, Olof Ramstrma, Klaus Mosbacha. Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions[J]. Analytical letters,1997,30(12):2123-2140. |
APA | Cong Yua, Olof Ramstrma,& Klaus Mosbacha.(1997).Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions.Analytical letters,30(12),2123-2140. |
MLA | Cong Yua,et al."Enantiomeric Recognition by Molecularly Imprinted Polymers Using Hydrophobic Interactions".Analytical letters 30.12(1997):2123-2140. |
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