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| Electrochemical determination of tryptophan at room-temperature ionic liquid-titanium carbide nanoparticle gel modified electrode | |
Li, Fei1 ; Zhang, Qing1; Pan, Dawei2; Lin, Mingyue2; Kang, Qi1; Kang, Q (reprint author), Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes, Jinan, Shandong 250014, Peoples R China. [email protected]
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| 发表期刊 | IONICS
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| ISSN | 0947-7047 |
| 2015-06-01 | |
| 卷号 | 21期号:6页码:1711-1718 |
| 关键词 | Tic nanoparTicles Ionic Liquid Tryptophan Electrochemical Characterizations Electrode Ionic Conductivity |
| DOI | 10.1007/s11581-014-1312-z |
| 产权排序 | [Li, Fei; Zhang, Qing; Kang, Qi] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes, Jinan, Shandong 250014, Peoples R China; [Pan, Dawei; Lin, Mingyue] Chinese Acad Sci, Key Lab Coastal Environm Processes & Ecol Remedia, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China |
| 作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
| 英文摘要 | The novel gel composite, based on the ground of ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate, BMIMPF6) and titanium carbide (TiC) nanoparticles, was used to modify glassy carbon electrode and applied to the electrochemical determination of tryptophan (trp). The physical and electrochemical characterizations of the BMIMPF6-TiC gel modified electrode were studied in detail by scanning electron microscopy, energy dispersive X-ray spectroscopy, cyclic voltammetry, and differential pulse voltammetry methods. Due to the large specific surface area and strong adsorption property of TiC nanoparticles, as well as the good ionic conductivity and strong electrocatalytic property of BMIMPF6, the oxidation peak current of trp at BMIMPF6-TiC gel modified electrode showed good linear relation with its concentrations ranging from 0.50 to 30 mu mol/L and 30 to 500 mu mol/L, respectively. The detection limit was 0.053 mu mol/L. More importantly, the BMIMPF6-TiC gel modified electrode had good anti-interference ability and can be successfully applied in the electrochemical determination of trp in real food samples. |
| 文章类型 | Article |
| 资助机构 | Chemistry ; Electrochemistry ; Physics |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | CARBON-PASTE ELECTRODE ; SELECTIVE POTENTIOMETRIC SENSOR ; SENSITIVE VOLTAMMETRIC SENSOR ; PYROLYTIC-GRAPHITE ELECTRODE ; POLY(VINYL CHLORIDE) MATRIX ; AMINO-ACIDS ; PVC MATRIX ; FOOD SAMPLES ; AMPEROMETRIC DETERMINATION ; CAPILLARY-ELECTROPHORESIS |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Physics |
| WOS记录号 | WOS:000354714900024 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/8795 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
| 通讯作者 | Kang, Q (reprint author), Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes, Jinan, Shandong 250014, Peoples R China. [email protected] |
| 作者单位 | 1.Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes 2.Chinese Acad Sci, Key Lab Coastal Environm Processes & Ecol Remedia, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS |
| 推荐引用方式 GB/T 7714 | Li, Fei,Zhang, Qing,Pan, Dawei,et al. Electrochemical determination of tryptophan at room-temperature ionic liquid-titanium carbide nanoparticle gel modified electrode[J]. IONICS,2015,21(6):1711-1718. |
| APA | Li, Fei,Zhang, Qing,Pan, Dawei,Lin, Mingyue,Kang, Qi,&Kang, Q .(2015).Electrochemical determination of tryptophan at room-temperature ionic liquid-titanium carbide nanoparticle gel modified electrode.IONICS,21(6),1711-1718. |
| MLA | Li, Fei,et al."Electrochemical determination of tryptophan at room-temperature ionic liquid-titanium carbide nanoparticle gel modified electrode".IONICS 21.6(2015):1711-1718. |
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| Electrochemical dete（765KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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