A simple approach for fabricating solid-contact ion-selective electrodes using nanomaterials as transducers
Liang, Rongning; Yin, Tanji; Qin, Wei; Qin, W (reprint author), Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China. [email protected]
发表期刊ANALYTICA CHIMICA ACTA
ISSN0003-2670
2015
卷号853页码:291-296
关键词Ion-selective Electrodes Solid Contacts Ion-to-electron Transducers Nanomaterials Ionic Liquids
DOI10.1016/j.aca.2014.10.033
产权排序[Liang, Rongning; Yin, Tanji; Qin, Wei] Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要A simple and robust approach for the development of solid-state ion-selective electrodes (ISEs) using nanomaterials as solid contacts is described. The electrodes are fabricated by using the mixture of an ionic liquid (IL) and a nanomaterial as intermediate layer, formed by melting the IL. Tetradodecylammonium tetrakis(4-chlorophenyl) borate (ETH 500) is chosen as an model of IL to provide strong adhesion between the inner glassy carbon electrode and the intermediate layer. Nanomaterials including single-walled carbon nanotubes (SWCNTs) and graphene were used as active ion-to-electron transducers between the glassy carbon electrode and the ionophore-doped ISE membrane. By using the proposed approach, the solid-contact Cu2+- and Pb2+-selective electrodes based on ETH 500/SWCNTs and ETH 500/graphene as transducers, respectively, have been fabricated. The proposed electrodes show detection limits in the nanomolar range and exhibit a good response time and excellent stability. (C) 2014 Elsevier B.V. All rights reserved.
文章类型期刊论文
资助机构Chemistry
收录类别SCI
语种英语
关键词[WOS]POTENTIOMETRIC SENSORS ; MEMBRANE-ELECTRODE ; CARBON NANOTUBES ; BUFFER LAYER ; PERFORMANCE ; LIQUIDS
研究领域[WOS]Instrument Developing Project of the Chinese Academy of Sciences [YZ201161] ; National Natural Science Foundation of China [41206087, 21475148] ; National 863 High Technology Project of the Ministry of Science and Technology of China [2007AA09Z103]
WOS记录号WOS:000345652000026
引用统计
被引频次:53[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/8678
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Qin, W (reprint author), Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China. [email protected]
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Liang, Rongning,Yin, Tanji,Qin, Wei,et al. A simple approach for fabricating solid-contact ion-selective electrodes using nanomaterials as transducers[J]. ANALYTICA CHIMICA ACTA,2015,853:291-296.
APA Liang, Rongning,Yin, Tanji,Qin, Wei,&Qin, W .(2015).A simple approach for fabricating solid-contact ion-selective electrodes using nanomaterials as transducers.ANALYTICA CHIMICA ACTA,853,291-296.
MLA Liang, Rongning,et al."A simple approach for fabricating solid-contact ion-selective electrodes using nanomaterials as transducers".ANALYTICA CHIMICA ACTA 853(2015):291-296.
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