| A rule to distinguish diastereomeric bianthrones by H-1 NMR | |
Ji, Nai-Yun1 ; Liang, Xiao-Rui1,2,3; Sun, Ran-Ran1,2; Miao, Feng-Ping1; Ji, NY (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China. [email protected]
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| 发表期刊 | RSC ADVANCES
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| ISSN | 2046-2069 |
| 2014 | |
| 卷号 | 4期号:15页码:7710-7715 |
| 关键词 | Aspergillus-wentii Absolute-configurations Bioactive Constituents Emodin Anthrone Identification Psorospermum Metabolites Derivatives Glaucus |
| 产权排序 | [Ji, Nai-Yun; Liang, Xiao-Rui; Sun, Ran-Ran; Miao, Feng-Ping] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China; [Liang, Xiao-Rui; Sun, Ran-Ran] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Liang, Xiao-Rui] Naval Aeronaut & Astronaut Univ, Yantai 264001, Peoples R China |
| 英文摘要 | Bianthrones have occurred widely in drug and material developments, but the stereochemistry remains in chaos so far due to the meso, racemic, and axis-rotating phenomena. Based on the computational and experimental results, an effective rule to distinguish between cis and trans bianthrones by H-1 NMR is concluded, which applies to both homo- and heterobianthrones.; Bianthrones have occurred widely in drug and material developments, but the stereochemistry remains in chaos so far due to the meso, racemic, and axis-rotating phenomena. Based on the computational and experimental results, an effective rule to distinguish between cis and trans bianthrones by H-1 NMR is concluded, which applies to both homo- and heterobianthrones. |
| 文章类型 | Article |
| 资助机构 | National Natural Science Foundations of China [41106136, 41106137]; 12th Five-Year Science and Technology Plan for Agriculture [2012BAD32B09]; Chinese Academy of Sciences for Key Topics in Innovation Engineering [KZCX2-YW-QN209] |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | ASPERGILLUS-WENTII ; ABSOLUTE-CONFIGURATIONS ; BIOACTIVE CONSTITUENTS ; EMODIN ANTHRONE ; IDENTIFICATION ; PSOROSPERMUM ; METABOLITES ; DERIVATIVES ; GLAUCUS |
| 研究领域[WOS] | Chemistry |
| WOS记录号 | WOS:000330241000051 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/7024 |
| 专题 | 海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室 |
| 通讯作者 | Ji, NY (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China. [email protected] |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Naval Aeronaut & Astronaut Univ, Yantai 264001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Nai-Yun,Liang, Xiao-Rui,Sun, Ran-Ran,et al. A rule to distinguish diastereomeric bianthrones by H-1 NMR[J]. RSC ADVANCES,2014,4(15):7710-7715. |
| APA | Ji, Nai-Yun,Liang, Xiao-Rui,Sun, Ran-Ran,Miao, Feng-Ping,&Ji, NY .(2014).A rule to distinguish diastereomeric bianthrones by H-1 NMR.RSC ADVANCES,4(15),7710-7715. |
| MLA | Ji, Nai-Yun,et al."A rule to distinguish diastereomeric bianthrones by H-1 NMR".RSC ADVANCES 4.15(2014):7710-7715. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| A rule to distinguis（498KB） | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |||
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