| Absolute Configurations of Unique Harziane Diterpenes from Trichoderma Species | |
Miao, Feng-Ping1 ; Liang, Xiao-Rui2; Yin, Xiu-Li1; Wang, Gang1; Ji, Nai-Yun1
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| 发表期刊 | ORGANIC LETTERS
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| ISSN | 1523-7060 |
| 2012-08-03 | |
| 卷号 | 14期号:15页码:3815-3817 |
| 关键词 | Density-functional Theory Secondary Metabolites |
| 产权排序 | [Miao, Feng-Ping; Yin, Xiu-Li; Wang, Gang; Ji, Nai-Yun] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; [Liang, Xiao-Rui] Naval Aeronaut & Astronaut Univ, Yantai 264001, Peoples R China |
| 通讯作者 | Ji, NY (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China.,[email protected] |
| 作者部门 | 海岸带生物学与生物资源利用所重点实验室 |
| 英文摘要 | Harzianone (2), a new harziane diterpene, was isolated from an alga-endophytic isolate of Trichoderma longibrachiatum. The structure and absolute configuration of 2 were unambiguously identified by NMR and mass spectrometric methods as well as quantum chemical calculations. The absolute configuration of harziandione (1) was supported by calculation of optical rotation, and the structure of isoharziandione was revised to 1 on the basis of C-13 NMR data comparison and calculation.; Harzianone (2), a new harziane diterpene, was isolated from an alga-endophytic isolate of Trichoderma longibrachiatum. The structure and absolute configuration of 2 were unambiguously identified by NMR and mass spectrometric methods as well as quantum chemical calculations. The absolute configuration of harziandione (1) was supported by calculation of optical rotation, and the structure of isoharziandione was revised to 1 on the basis of C-13 NMR data comparison and calculation. |
| 文章类型 | Article |
| 资助机构 | National Natural Science Foundation of China[41106137, 41106136]; Chinese Academy of Sciences for Key Topics in Innovation Engineering[KZCX2-YW-QN209, KSCX2-EW-G-12B] |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| 关键词[WOS] | DENSITY-FUNCTIONAL THEORY ; SECONDARY METABOLITES |
| 研究领域[WOS] | Chemistry |
| WOS记录号 | WOS:000307041600001 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/6088 |
| 专题 | 海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室 |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China 2.Naval Aeronaut & Astronaut Univ, Yantai 264001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Miao, Feng-Ping,Liang, Xiao-Rui,Yin, Xiu-Li,et al. Absolute Configurations of Unique Harziane Diterpenes from Trichoderma Species[J]. ORGANIC LETTERS,2012,14(15):3815-3817. |
| APA | Miao, Feng-Ping,Liang, Xiao-Rui,Yin, Xiu-Li,Wang, Gang,&Ji, Nai-Yun.(2012).Absolute Configurations of Unique Harziane Diterpenes from Trichoderma Species.ORGANIC LETTERS,14(15),3815-3817. |
| MLA | Miao, Feng-Ping,et al."Absolute Configurations of Unique Harziane Diterpenes from Trichoderma Species".ORGANIC LETTERS 14.15(2012):3815-3817. |
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