Determination of Trace Copper in Water Samples by Anodic Stripping Voltammetry at Gold Microelectrode
Zhuang, Jianmei1; Zhang, Li2,3,4; Lu, Wenjing2,3,4; Shen, Dazhong1; Zhu, Rilong5; Pan, Dawei2,3
发表期刊INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
2011-10-01
卷号6期号:10页码:4690-4699
关键词Gold Microelectrode Copper Anodic Stripping Voltammetry Water Samples
产权排序[Jianmei Zhuang; Dazhong Shen]The Key Lab in Molecular and Nano-materials Probes of the Ministry of Education of China, College of Chemistry, Chemical Engineering and Materials Science, Shangdong Normal University, Jinan 250014, P.R. China; [Li Zhang; Wenjing Lu; Dawei Pan]CAS and Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, P.R. China; [Li Zhang; Wenjing Lu]Graduate School of the Chinese Academy of Sciences, Beijing 100039, P.R. China; [Rilong Zhu]Hunan Province Environmental Monitoring Centre, Changsha 410014, P.R. China
通讯作者[Dawei Pan]CAS and Shandong Provincial Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, P.R. China. [email protected]
作者部门环境化学实验室 
英文摘要The applicability of gold microelectrode of 25 mu m diameter for electrochemical determination of trace copper ions (Cu(2+)) in water samples by anodic stripping voltammetry (ASV) has been demonstrated. The analysis of Cu(2+) at gold microelectrode includes two steps. Cu(2+) ions are firstly reduced and accumulated on the microelectrode surface during an accumulation step, then oxidized during the positive potential sweep. Due to the rapid mass transporting and low background current of gold microelectrode, low detection limit (0.3 nM) and wide linear range (1.0-90 nM) can be obtained. The practical application of gold microelectrode was verified by determination of trace level of Cu(2+) in tap water, lake water and commercial drinking water samples.
文章类型Article
收录类别SCI
语种英语
关键词[WOS]CARBON-PASTE ELECTRODE ; SOLID-PHASE EXTRACTION ; NATURAL-WATERS ; HUMAN SWEAT ; SILICA-GEL ; MERCURY ; ARRAYS ; ELECTROCHEMISTRY ; PRECONCENTRATION ; IONS
研究领域[WOS]Electrochemistry
WOS记录号WOS:000297502500021
引用统计
被引频次:20[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/5149
专题中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
中国科学院海岸带环境过程与生态修复重点实验室
作者单位1.Shangdong Normal Univ, Key Lab Mol & Nanomat Probes, Minist Educ China, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China
2.Chinese Acad Sci, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
3.Chinese Acad Sci, CAS, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
4.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
5.Hunan Prov Environm Monitoring Ctr, Changsha 410014, Hunan, Peoples R China
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Zhuang, Jianmei,Zhang, Li,Lu, Wenjing,et al. Determination of Trace Copper in Water Samples by Anodic Stripping Voltammetry at Gold Microelectrode[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2011,6(10):4690-4699.
APA Zhuang, Jianmei,Zhang, Li,Lu, Wenjing,Shen, Dazhong,Zhu, Rilong,&Pan, Dawei.(2011).Determination of Trace Copper in Water Samples by Anodic Stripping Voltammetry at Gold Microelectrode.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,6(10),4690-4699.
MLA Zhuang, Jianmei,et al."Determination of Trace Copper in Water Samples by Anodic Stripping Voltammetry at Gold Microelectrode".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 6.10(2011):4690-4699.
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