Design and Synthesis of Fluorine-Containing Embedded Carbon Dots Stationary Phase for Separation of Versatile Analytes

doi:10.1021/acs.analchem.4c02411

	Design and Synthesis of Fluorine-Containing Embedded Carbon Dots Stationary Phase for Separation of Versatile Analytes
	Song, Zhihua 1; Wu, Wenpu 1; Sui, Lei 1; Han, Xinyan 1; Xu, Hui 1; Yang, Gangqiang 1; Zhang, Peng 1; Zhou, Na 2; Chen, Lingxin2,3 ; Li, Jinhua2
发表期刊	ANALYTICAL CHEMISTRY
ISSN	0003-2700
	2024-10-04
卷号	96 期号:42 页码:16590-16598
DOI	10.1021/acs.analchem.4c02411
通讯作者	Song, Zhihua([email protected]) ; Li, Jinhua([email protected])
英文摘要	Thus far, numerous new stationary phases have been developed. A fluorine-containing embedded carbon dots (F3-CDs-SiO2) stationary phase was first designed and synthesized. The resulting F3-CDs-SiO2 stationary phase was characterized carefully by scanning electron microscopy, transmission electron microscopy, elemental analysis, X-ray photoelectron spectroscopy, and Brunauer-Emmett-Teller experiment. The F3-CDs-SiO2 stationary phase was slurry packed into the HPLC column (150 x 2.1 mm) for evaluation. Furthermore, the F3-CDs-SiO2 column was successfully used for separation of pesticides, nucleosides, sulfonamides, alkaloids, and alkylbenzenes. The retention mechanism (including hydrophobic interaction, F-F, hydrogen bond interaction, ion-exchange, dipole-dipole interaction, electrostatic interaction, etc.) was investigated carefully. Meanwhile, the F3-SiO2 stationary phase was synthesized and used to evaluate the role of CDs. Furthermore, various commercial stationary phases (including amino-SiO2, diol-SiO2, C18-SiO2, and PFP-SiO2) were used for comparison. Moreover, the F3-CDs-SiO2 column possessed good repeatability, reproducibility, and stability in separation of versatile analytes.
资助机构	National Natural Science Foundation of China ; Shandong Provincial Natural Science Foundation ; Project of Yantai Growth Drivers Conversion Research Institute ; Yantai Science and Technology Achievement Transfer and Transformation Demonstration Base ; Youth Innovation Team Plan of Shandong Province
收录类别	SCI
语种	英语
关键词[WOS]	LIQUID-CHROMATOGRAPHY ; SILICA
研究领域[WOS]	Chemistry
WOS记录号	WOS:001330129700001
引用统计
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/37138
专题	中国科学院海岸带环境过程与生态修复重点实验室中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心支撑部门_所级公共技术服务中心
通讯作者	Song, Zhihua; Li, Jinhua
作者单位	1.Yantai Univ, Sch Pharm, Collaborat Innovat Ctr Adv Drug Delivery Syst & Bi, Key Lab Mol Pharmacol & Drug Evaluat,Minist Educ, Yantai 264005, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn & Technol, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China 3.Binzhou Med Univ, Sch Pharm, Yantai 264003, Peoples R China
推荐引用方式 GB/T 7714	Song, Zhihua,Wu, Wenpu,Sui, Lei,et al. Design and Synthesis of Fluorine-Containing Embedded Carbon Dots Stationary Phase for Separation of Versatile Analytes[J]. ANALYTICAL CHEMISTRY,2024,96(42):16590-16598.
APA	Song, Zhihua.,Wu, Wenpu.,Sui, Lei.,Han, Xinyan.,Xu, Hui.,...&Li, Jinhua.(2024).Design and Synthesis of Fluorine-Containing Embedded Carbon Dots Stationary Phase for Separation of Versatile Analytes.ANALYTICAL CHEMISTRY,96(42),16590-16598.
MLA	Song, Zhihua,et al."Design and Synthesis of Fluorine-Containing Embedded Carbon Dots Stationary Phase for Separation of Versatile Analytes".ANALYTICAL CHEMISTRY 96.42(2024):16590-16598.