Spherical covalent organic frameworks supported black phosphorus@Au nanocatalysts for nitrophenol hydrogenation in a high efficiently flow-through process

doi:10.1016/j.apsusc.2022.155723

	Spherical covalent organic frameworks supported black phosphorus@Au nanocatalysts for nitrophenol hydrogenation in a high efficiently flow-through process
	Zheng, Yaochen 1; Qi, Xiaole 1; Xiao, Fenyan 3; Wang, Fushuai 1; Wang, Ning2
发表期刊	APPLIED SURFACE SCIENCE
ISSN	0169-4332
	2023-02-15
卷号	611 页码:9
关键词	Spherical covalent organic frameworks Black phosphorus Au nanoparticles Flow -through 4-Nitrophenol
DOI	10.1016/j.apsusc.2022.155723
通讯作者	Wang, Ning([email protected])
英文摘要	Exfoliated black phosphorus (BP) nanosheets possessing unique electron-reservoir and electron-donor properties could fast electron transfer, promising as a cocatalyst for catalysis. However, the catalytic process was limited by the morphology of BP nanosheets because the continuous pressure deriving from the effluent would dense the channel of stacked BP nanosheets. In this work, spherical covalent organic frameworks were synthesized and used as a platform to support BP nanosheets/Au nanocatalysts. The prepared heterostructure was applied to catalytic reduction of 4-nitrophenol under a flow-through catalytic process. An optimized permeation flux of 2500 L/m- 2(- \|-)h-1 (LMH) and a reduction efficiency of 99 % was achieved. Furthermore, only 0.064 wt% of Au NPs was released after testing for 24 h. Our straightforward strategy to solve the issues suffering from the continuous treatment of effluent would facilitate the application of novel nanomaterials in environmental remediation.
资助机构	Na-tional Natural Science Foundation of China ; Natural Science Foundation of Shandong Province ; Fundamental Research Projects of Science & Technology Innovation and Development Plan in Yantai City
收录类别	SCI
语种	英语
关键词[WOS]	CATALYTIC-REDUCTION ; METAL NANOPARTICLES ; 4-NITROPHENOL ; MICROSPHERES
研究领域[WOS]	Chemistry ; Materials Science ; Physics
WOS记录号	WOS:000893091800001
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/37001
专题	中国科学院海岸带环境过程与生态修复重点实验室中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
通讯作者	Wang, Ning
作者单位	1.Yantai Univ, Yantai 264005, Shandong, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Shandong, Peoples R China 3.Yantai Vocat Coll, Yantai 264670, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Yaochen,Qi, Xiaole,Xiao, Fenyan,et al. Spherical covalent organic frameworks supported black phosphorus@Au nanocatalysts for nitrophenol hydrogenation in a high efficiently flow-through process[J]. APPLIED SURFACE SCIENCE,2023,611:9.
APA	Zheng, Yaochen,Qi, Xiaole,Xiao, Fenyan,Wang, Fushuai,&Wang, Ning.(2023).Spherical covalent organic frameworks supported black phosphorus@Au nanocatalysts for nitrophenol hydrogenation in a high efficiently flow-through process.APPLIED SURFACE SCIENCE,611,9.
MLA	Zheng, Yaochen,et al."Spherical covalent organic frameworks supported black phosphorus@Au nanocatalysts for nitrophenol hydrogenation in a high efficiently flow-through process".APPLIED SURFACE SCIENCE 611(2023):9.