Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol

YIC-IR

	Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol
	Fang Deren 1; Ren Wanzhong 2; Liu Zhongmin 1; Xu Xiufeng 2; Xu Lei 1; Lue Hongying 2; Liao Weiping 2; Zhang Huimin 2
发表期刊	JOURNAL OF NATURAL GAS CHEMISTRY
ISSN	1003-9953
	2009
卷号	18 期号:2 页码:179-182
关键词	COPPER-CONTAINING CATALYSTS CO-MO CATALYST OXIDATION-STATE MCM-41 HYDRODESULFURIZATION CYCLOHEXANOL ISOPROPANOL SITES Cu-Zn-Al2O3 mesoporous materials dehydrogenation of 2-butanol catalyst
英文摘要	A series of mesoporous Cu-Zn-Al2O3 materials have been synthesized at ambient temperature and their structure was characterized by XRD, N-2 physical adsorption and TPR techniques. Their catalytic applications for the dehydrogenation of 2-butanol to methyl ethyl ketone (MEK) were evaluated in a fixed-bed flow reactor at atmospheric pressure. It is demonstrated from the XRD patterns that both the as-synthesized samples and calcined samples have the typical XRD patterns of meso-structured materials and the results of N2O chemical adsorption showed that Cu was embedded in the framework of the mesoporous materials and homogeneously dispersed in the mesoporous Cu-Zn-Al2O3 materials. The catalytic activity of 2-butanol dehydrogenation was varied in the order of CZA(10)< CZA(CP)< CZA(20)< CZA(30) while the selectivity of MEK was increased in the order of CZA(CP)CZA(10)< CZA(20)< CZA(30).
收录类别	CSCD
语种	英语
CSCD记录号	CSCD:3613846
引用统计
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/34984
专题	中国科学院烟台海岸带研究所
作者单位	1.中国科学院 2.中国科学院烟台海岸带研究所
推荐引用方式 GB/T 7714	Fang Deren,Ren Wanzhong,Liu Zhongmin,et al. Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol[J]. JOURNAL OF NATURAL GAS CHEMISTRY,2009,18(2):179-182.
APA	Fang Deren.,Ren Wanzhong.,Liu Zhongmin.,Xu Xiufeng.,Xu Lei.,...&Zhang Huimin.(2009).Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol.JOURNAL OF NATURAL GAS CHEMISTRY,18(2),179-182.
MLA	Fang Deren,et al."Synthesis and applications of mesoporous Cu-Zn-Al2O3 catalyst for dehydrogenation of 2-butanol".JOURNAL OF NATURAL GAS CHEMISTRY 18.2(2009):179-182.