一种基于花菁的有机化合物及其应用
其他名称Organic compound based on cyanine and application thereof
专利类型发明
专利号2017110890094
于法标; 王蕊; 郭晓艳; 陈令新
专利权人中国科学院烟台海岸带研究所
申请日期2017-11-08
2020-07-31
专利状态授权
授权国家中国
摘要本发明涉及单胺氧化酶的检测,具体地说是一种基于花菁的有机化合物及其应用。化合物如结构式Ⅰ所示,以所述化合物作为比率的检测线粒体外膜上单胺氧化酶A(MAO‑A)的荧光探针。本发明比率检测MAO‑A的荧光探针的这类化合物,在MAO‑A的存在下,响应基团作为MAO‑A的底物,在FAD辅酶的作用下,通过MAO‑A催化的甲氨基氧化成醛丙醛部分通过β消除和一个CO2的自发释放,荧光团被释放。本发明用于比率检测MAO‑A,在MAO‑A存在下对应的荧光波长发生明显位移,可用于MAO‑A的检测,并可大大降低外部检测条件的干扰,提高检测精度。此发明比率检测MAO‑A荧光探针的这类化合物,在MAO‑A存在时,紫外吸收亦发生明显变化,可同时用紫外分光光度计及肉眼进行检测。
其他摘要The invention relates to detection of monoamine oxidase, and specifically relates to an organic compound based on cyanine and an application of the organic compound. The organic compound is shown in astructural formula I, and the compound is used as a fluorescent probe for ratio detection of monoamine oxidase A (MAO-A) on mitochondrial outer membranes. According to the compound used as the fluorescent probe for the ratio detection of the MAO-A, in the presence of the MAO-A, a response group is used as a substrate of the MAO-A; and under the action of an FAD coenzyme, methylamino is oxidized to form an aldehyde group under catalysis of the MAO-A, beta-elimination is carried out on a propionaldehyde part, and CO2 is released spontaneously, so that a fluorescent group is released. The organic compound disclosed by the invention is used for the ratio detection of the MAO-A, and in the presence of the MAO-A, obvious displacement of the corresponding fluorescence wavelength occurs, so thatthe organic compound can be used for the detection of the MAO-A, the interference of external detection conditions can be greatly reduced, and the detection precision is improved. According to the compound used as the fluorescent probe for the ratio detection of the MAO-A, when the MAO-A exists, the ultraviolet absorption changes obviously, and an ultraviolet spectrophotometer and naked eyes can be simultaneously used for detection.
申请号2017110890094
公开(公告)号CN107903289B
IPC 分类号C07F9/6558 ; C09K11/06 ; G01N21/33 ; G01N21/64
专利代理人李颖 ; 周秀梅
代理机构沈阳科苑专利商标代理有限公司 21002
CPC分类号C07F9/65583 ; C09K11/06 ; C09K2211/1059 ; G01N21/33 ; G01N21/6428 ; G01N21/6486
文献类型专利
条目标识符http://ir.yic.ac.cn/handle/133337/33863
专题中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
作者单位中国科学院烟台海岸带研究所
推荐引用方式
GB/T 7714
于法标,王蕊,郭晓艳,等. 一种基于花菁的有机化合物及其应用. 2017110890094[P]. 2020-07-31.
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