All-Solid-State Polymeric Membrane Ion-Selective Electrodes Based on NiCo(2)S(4 )as a Solid Contact

doi:10.1021/acs.analchem.1c04748

	All-Solid-State Polymeric Membrane Ion-Selective Electrodes Based on NiCo(2)S(4 )as a Solid Contact
	Li, Yanhong 1,2,5; Li, Jinghui1,2 ; Qin, Wei1,2,3,4
发表期刊	ANALYTICAL CHEMISTRY
ISSN	0003-2700
	2022-03-01
卷号	94 期号:8 页码:3574-3580
DOI	10.1021/acs.analchem.1c04748
英文摘要	The performance criteria for the design of all-solid-state ion-selective electrodes mainly include high electrode-to-electrode reproducibilityand a low potential drift. Here, we introduce nickel cobalt sulfide (NiCo2S4)as a solid contact for ion-to-electron transduction based on multiple redoxcouples. NiCo2S4materials with different morphologies can be preparedthrough a facile hydrothermal/solvothermal method. A NiCo2S4-based solid-contact Ca2+-ISE has been developed, which exhibits a Nernstian slope of27.5 +/- 0.2 mV/dec in the activity range from 1.0x10-6to 2.9x10-2Mwith a detection limit of 5.0x10-7M. A variation of the standard potentialE degrees for eight individual solid-contact electrodes can be obtained as low as 0.35mV. Due to the synergistic effect of cobalt and nickel ions in the ternarysulfide, an excellent redox capacitance (565 mu F) of the buried solid contactcoated with the ion-selective membrane can be achieved and is much largerthan those obtained from other redox solid-contact materials reported so far, thus yielding a high potential stability of 2.2 +/- 0.4 mu V/h. In addition, the NiCo2S4-based solid-contact Ca2+-ISE shows a reduced water layer at the sensing membrane/NiCo2S4interfaceand provides an excellent resistance to the interferences from light, O2, and CO2. The proposed strategy utilizing NiCo2S4as a solidcontact is a promising alternative for the fabrication of calibration-free ASS-ISEs.
收录类别	SCI
语种	英语
关键词[WOS]	NICO2S4 ; CARBON ; PERFORMANCE ; COEFFICIENTS ; TRANSDUCER ; STABILITY ; GRAPHENE
研究领域[WOS]	Chemistry
WOS记录号	WOS:000792496600019
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/31042
专题	中国科学院海岸带环境过程与生态修复重点实验室中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境过程实验室
通讯作者	Li, Jinghui; Qin, Wei
作者单位	1.Chinese Acad Sci, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China 2.YICCAS, Yantai Inst Coastal Zone Res YIC, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 266237, Peoples R China 4.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Yanhong,Li, Jinghui,Qin, Wei. All-Solid-State Polymeric Membrane Ion-Selective Electrodes Based on NiCo(2)S(4 )as a Solid Contact[J]. ANALYTICAL CHEMISTRY,2022,94(8):3574-3580.
APA	Li, Yanhong,Li, Jinghui,&Qin, Wei.(2022).All-Solid-State Polymeric Membrane Ion-Selective Electrodes Based on NiCo(2)S(4 )as a Solid Contact.ANALYTICAL CHEMISTRY,94(8),3574-3580.
MLA	Li, Yanhong,et al."All-Solid-State Polymeric Membrane Ion-Selective Electrodes Based on NiCo(2)S(4 )as a Solid Contact".ANALYTICAL CHEMISTRY 94.8(2022):3574-3580.