Analytical intercomparison results from the 1990 Intergovernmental Oceanographic Commission open-ocean baseline survey for trace metals: Atlantic Ocean | |
W. M. Landinga ; G. A. Cutterb ; J. A. Dalzielc ; A. R. Flegald ; R. T. Powella ; D. Schmidte ; A. Shillerf ; P. Stathamg ; S. Westerlundh and J. Resing | |
发表期刊 | Marine Chemistry |
ISSN | 0304-4203 |
1995 | |
卷号 | 49期号:4页码:253-265 |
中文摘要 | “Dissolved” (< 0.4 μm filtered) and “total dissolvable” (unfiltered) trace element samples were collected using “clean” sampling techniques from four vertical profiles in the eastern Atlantic Ocean on the first IOC Trace Metals Baseline expedition. The analytical results obtained by 9 participating laboratories for Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, and Se on samples from station 4 in the northeast Atlantic have been evaluated with respect to accuracy and precision (intercomparability). The data variability among the reporting laboratories was expressed as 2 × SD for a given element and depth, and was comparable to the 95% confidence interval reported for the NASS seawater reference standards (representing analytical variability only). The discrepancies between reporting laboratories appear to be due to inaccuracies in standardization (analytical calibration), blank correction, and/or extraction efficiency corrections.Several of the sampling bottles used at this station were not adequately pre-cleaned (anomalous Pb results). The sample filtration process did not appear to have been a source of contamination for either dissolved or particulate trace elements. The trace metal profiles agree in general with previously reported profiles from the Atlantic Ocean. We conclude that the sampling and analytical methods we have employed for this effort, while still in need of improvement, are sufficient for obtaining accurate concentration data on most trace metals in the major water masses of the oceans, and to enable some evaluation of the biogeochemical cycling of the metals. |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/2985 |
专题 | 科研共享资源 |
推荐引用方式 GB/T 7714 | W. M. Landinga,G. A. Cutterb,J. A. Dalzielc,et al. Analytical intercomparison results from the 1990 Intergovernmental Oceanographic Commission open-ocean baseline survey for trace metals: Atlantic Ocean[J]. Marine Chemistry,1995,49(4):253-265. |
APA | W. M. Landinga.,G. A. Cutterb.,J. A. Dalzielc.,A. R. Flegald.,R. T. Powella.,...&S. Westerlundh and J. Resing.(1995).Analytical intercomparison results from the 1990 Intergovernmental Oceanographic Commission open-ocean baseline survey for trace metals: Atlantic Ocean.Marine Chemistry,49(4),253-265. |
MLA | W. M. Landinga,et al."Analytical intercomparison results from the 1990 Intergovernmental Oceanographic Commission open-ocean baseline survey for trace metals: Atlantic Ocean".Marine Chemistry 49.4(1995):253-265. |
条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Analytical intercomp(984KB) | 限制开放 | -- | 请求全文 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论