Real-time monitoring of the dissolution of silver nanoparticles by using a solid-contact Ag+-selective electrode

doi:10.1016/j.aca.2019.12.022

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	Real-time monitoring of the dissolution of silver nanoparticles by using a solid-contact Ag+-selective electrode
	Yin, TJ; Han, TT ; Li, CB ; Qin, W; Bobacka, J
发表期刊	ANALYTICA CHIMICA ACTA
ISSN	0003-2670
	2020-03-08
卷号	1101 页码:50-57
关键词	Solid-contact Ag+-selective electrode Mesoporous carbon Spontaneous dissolution Stimulated dissolution Ag+
研究领域	Chemistry, Analytical
DOI	10.1016/j.aca.2019.12.022
产权排序	[Yin, Tanji; Qin, Wei] Chinese Acad Sci, Shandong Key Lab Coastal Environm Proc, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China; [Yin, Tanji; Han, Tingting; Li, Changbai; Bobacka, Johan] Abo Akad Univ, Johan Gadolin Proc Chem Ctr, Lab Mol Sci & Engn, Biskopsgatan 8, FIN-20500 Turku, Finland; [Yin, Tanji; Qin, Wei] Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 266200, Peoples R China
作者部门	海岸带环境过程实验室
英文摘要	The dissolution kinetics of silver nanoparticles (Ag NPs) to Ag+ ions is a critical factor determining the toxicity of silver nanoparticles. In this work, a solid-contact Ag+-selective electrode (Ag+-ISE) is fabricated and used to monitor the dissolution of Ag NPs. Ordered mesoporous carbon is compared with disordered mesoporous carbon as the solid-contact material for the Ag+-ISE. The ordered mesoporous carbon based solid-contact Ag+-ISE shows a linear potential response in the range of 1.0 x 10(-6)-1.0 x 10(-3) M AgNO3 with the slope of 55.6 +/- 0.8 mV/dec (n = 7) and the detection limit of 10(-6.8) M. The solid-contact Ag+-ISE is used to monitor the concentration changes of Ag+ during spontaneous dissolution of Ag NPs in deionized water, and the dissolution kinetics of Ag NPs is consistent with that obtained by inductively coupled plasma-mass spectrometry (ICP-MS). Stimulated dissolution of Ag NPs induced by addition of H2O2 to the Ag NP solution is also investigated by the proposed solid-contact Ag+-ISE. This work provides a fast tool for charactering the dissolution of Ag NPs to Ag+ in real time, which is important for studying the toxicology of nanoparticles. (C) 2019 Elsevier B.V. All rights reserved.
文章类型	Article
资助机构	Johan Gadolin Scholarship by the Johan Gadolin Process Chemistry Centre at Abo Akademi University ; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [41706110]
收录类别	SCI
语种	英语
关键词[WOS]	MESOPOROUS CARBON ; TOXICITY ; STABILITY ; IONS ; SPECIATION ; IMPACT
研究领域[WOS]	Chemistry, Analytical
WOS记录号	WOS:000510835500006
引用统计	被引频次：20[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/24740
专题	中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境过程实验室中国科学院海岸带环境过程与生态修复重点实验室
作者单位	1.Chinese Acad Sci, Shandong Key Lab Coastal Environm Proc, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China; 2.Abo Akad Univ, Johan Gadolin Proc Chem Ctr, Lab Mol Sci & Engn, Biskopsgatan 8, FIN-20500 Turku, Finland; 3.Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 266200, Peoples R China
推荐引用方式 GB/T 7714	Yin, TJ,Han, TT,Li, CB,et al. Real-time monitoring of the dissolution of silver nanoparticles by using a solid-contact Ag+-selective electrode[J]. ANALYTICA CHIMICA ACTA,2020,1101:50-57.
APA	Yin, TJ,Han, TT,Li, CB,Qin, W,&Bobacka, J.(2020).Real-time monitoring of the dissolution of silver nanoparticles by using a solid-contact Ag+-selective electrode.ANALYTICA CHIMICA ACTA,1101,50-57.
MLA	Yin, TJ,et al."Real-time monitoring of the dissolution of silver nanoparticles by using a solid-contact Ag+-selective electrode".ANALYTICA CHIMICA ACTA 1101(2020):50-57.

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