| Synthesis, characterization, and the antioxidant activity of N,N,N-trimethyl chitosan salts | |
Zhang, Jingjing; Tan, Wenqiang ; Wang, Gang; Yin, Xiuli; Li, Qing; Dong, Fang; Guo, Zhanyong
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| 发表期刊 | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
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| ISSN | 0141-8130 |
| 2018-10-15 | |
| 卷号 | 118期号:A页码:9-14 |
| 关键词 | Antioxidant activity N,N,N-trimethyl chitosan salts Structure characteristics |
| 研究领域 | Biochemistry & Molecular Biology ; Chemistry ; Polymer Science |
| DOI | 10.1016/j.ijbiomac.2018.06.018 |
| 产权排序 | [Zhang, Jingjing; Tan, Wenqiang; Wang, Gang; Yin, Xiuli; Li, Qing; Dong, Fang; Guo, Zhanyong] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China; [Zhang, Jingjing; Tan, Wenqiang; Guo, Zhanyong] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 作者部门 | 海岸带生物资源高效利用研究与发展中心 |
| 英文摘要 | Chitosan, possessing excellent properties, has been drawing broad attention. For the further utilization of chitosan, chemical modification is performed in improving its water solubility and the bioactivities. In the current study, four N,N,N-trimethyl chitosan salts, including N,N,N-trimethyl chitosan citrate (TMCSCi), N,N,N-trimethyl chitosan acetylsalicylate (TMCSAc), N,N,N-trimethyl chitosan ascorbate (TMCSAs), and N,N,N-trimethyl chitosan gallate (TMCSGa), were prepared via N,N,N-trimethyl chitosan iodide (TMCSI). The as-prepared products were characterized by FT-IR and H-1 NMR. Meanwhile, the degrees of substitution were calculated by elemental analysis results. Furthermore, scavenging activities (against DPPH radicals and superoxide radicals) test and reducing power test were selected to evaluate the antioxidant property of N,N,N-trimethyl chitosan salts in vitro. The results indicated that TMCSAs and TMCSGa displayed excellent activity, probably due to the enhancement of ascorbate and gallate in antioxidant activity. However, because of the weak antioxidant property of citrate and acetylsalicylate, the activity was lower for TMCSCi and TMCSAc. For example, in the DPPH radicals scavenging assay, the scavenging rates of chitosan, TMCSI, TMCSCi, TMCSAc, TMCSAs, and TMCSGa were 25.22, 84.11, 6.90, 2.70, 94.92, and 96.75% at 0.4 mg/mL, respectively. Generally, TMCSAs and TMCSGa could be regarded as a potential source of antioxidants. (C) 2018 Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 资助机构 | National Natural Science Foundation of China [41576156] ; Natural Science Foundation of Shandong Province of China [ZR2017BD015] ; Yantai Science and Technology Development Plan [2015ZH078] ; Technology Research Funds Projects of Ocean [2015418022-3] |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | ASCORBIC-ACID ; MOLECULAR-WEIGHT ; GALLIC ACID ; CITRIC-ACID ; IN-VITRO ; ANTIFUNGAL ; DERIVATIVES ; NANOPARTICLES ; RESPONSES ; PROPERTY |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry, Applied ; Polymer Science |
| WOS记录号 | WOS:000445170200002 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/24550 |
| 专题 | 海岸带生物学与生物资源利用重点实验室_海岸带生物资源高效利用研究与发展中心 海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室 中国科学院海岸带环境过程与生态修复重点实验室_污染过程与控制实验室 |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China; 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jingjing,Tan, Wenqiang,Wang, Gang,et al. Synthesis, characterization, and the antioxidant activity of N,N,N-trimethyl chitosan salts[J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,2018,118(A):9-14. |
| APA | Zhang, Jingjing.,Tan, Wenqiang.,Wang, Gang.,Yin, Xiuli.,Li, Qing.,...&Guo, Zhanyong.(2018).Synthesis, characterization, and the antioxidant activity of N,N,N-trimethyl chitosan salts.INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,118(A),9-14. |
| MLA | Zhang, Jingjing,et al."Synthesis, characterization, and the antioxidant activity of N,N,N-trimethyl chitosan salts".INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 118.A(2018):9-14. |
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