Novel Aromatic Polyamides Containing 2-Diphenylamino-(9,9-dimethylamine) Units as Multicolored Electrochromic and High-Contrast Electrofluorescent Materials

doi:10.1002/pola.28400

	Novel Aromatic Polyamides Containing 2-Diphenylamino-(9,9-dimethylamine) Units as Multicolored Electrochromic and High-Contrast Electrofluorescent Materials
	Sun, Ningwei ; Zhou, Ziwei ; Chao, Danming ; Chu, Xiaojing ; Du, Yinlong ; Zhao, Xiaogang ; Wang, Daming ; Chen, Chunhai ; Wang, DM (reprint author), Jilin Univ, Dept Chem, Alan G MacDiarmid Lab, Changchun 130012, Peoples R China. [email protected]
发表期刊	JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN	0887-624X
	2017
卷号	55 期号:2 页码:213-222
关键词	Electrochemistry Electrochromism Electrofluorescence Fluorene Polyamides Triphenylamine
DOI	10.1002/pola.28400
产权排序	[Sun, Ningwei; Chao, Danming; Du, Yinlong; Zhao, Xiaogang; Wang, Daming; Chen, Chunhai] Jilin Univ, Dept Chem, Alan G MacDiarmid Lab, Changchun 130012, Peoples R China; [Zhou, Ziwei] Jilin Univ, Dept Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China; [Chu, Xiaojing] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264100, Peoples R China
作者部门	中科院海岸带环境过程与生态修复重点实验室
英文摘要	A series of electrochromic and photoluminescenceactive polyamides 4a-4e were prepared from a novel dicarboxylic acid, N,N-di(4-carboxyphenyl)-2-amino-9,9-dimethylfluorene, and five diamines via a condensation polymerization. These polyamides were amorphous and readily soluble in many solvents. The glass transition temperatures were in the range of 281-339 degrees C and the 10% weight loss temperatures in nitrogen were in excess of 490 degrees C. The polyamides exhibited strong fluorescence in either solution or solid states. The polyamides 4a-4d showed reversible electrochemical redox with color changing from colorless to grey-green. Specially, the polyamide 4e with 2-diphenylamino-(9,9-dimethylamine) group in both diamine and dicarboxylic acid residues exhibited multicolored electrochromic behaviors. Furthermore, the fluorescence of these polyamides could be reversibly electroswitched with a high contrast up to 221.4, enabling their potential applications in dual-switching electrochromic/electrofluorescent materials. (C) 2016 Wiley Periodicals, Inc.
文章类型	Article
收录类别	SCI
语种	英语
关键词[WOS]	TUNGSTEN-OXIDE ; HOLE TRANSPORT ; TRIPHENYLAMINE ; DEVICES ; POLYMERS ; DYE ; FLUORENE ; MOIETIES ; DESIGN ; FILMS
研究领域[WOS]	Polymer Science
WOS记录号	WOS:000389526100003
引用统计	被引频次：27[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/19269
专题	中国科学院烟台海岸带研究所知识产出
通讯作者	Wang, DM (reprint author), Jilin Univ, Dept Chem, Alan G MacDiarmid Lab, Changchun 130012, Peoples R China. [email protected]
作者单位	1.Jilin Univ, Dept Chem, Alan G MacDiarmid Lab, Changchun 130012, Peoples R China 2.Jilin Univ, Dept Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China 3.Jilin Univ, Dept Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China 4.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264100, Peoples R China
推荐引用方式 GB/T 7714	Sun, Ningwei,Zhou, Ziwei,Chao, Danming,et al. Novel Aromatic Polyamides Containing 2-Diphenylamino-(9,9-dimethylamine) Units as Multicolored Electrochromic and High-Contrast Electrofluorescent Materials[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2017,55(2):213-222.
APA	Sun, Ningwei.,Zhou, Ziwei.,Chao, Danming.,Chu, Xiaojing.,Du, Yinlong.,...&Wang, DM .(2017).Novel Aromatic Polyamides Containing 2-Diphenylamino-(9,9-dimethylamine) Units as Multicolored Electrochromic and High-Contrast Electrofluorescent Materials.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,55(2),213-222.
MLA	Sun, Ningwei,et al."Novel Aromatic Polyamides Containing 2-Diphenylamino-(9,9-dimethylamine) Units as Multicolored Electrochromic and High-Contrast Electrofluorescent Materials".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 55.2(2017):213-222.

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